Supplement to the proof of the clausius inequality 克劳修斯不等式证明的一点补充
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Clausius - clapeyron equation 克拉佩龙方程
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Since clausius firstly put the entropy theory forward in the year of 1865 , it has always been developing 熵理论自从1865年被克劳修斯提出以后一直不断地发展。
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The adsorption isotherm of neptunium on silica gel correspond to the form of langmuir isotherm . according to clausius - claperon equation , from the slope in inkd vs 1 / t plot , adsorption heat could be estimated . from the data of adsorption heat it is concluded that the adsorption of neptunium on silica gel in nitric acid solutions belongs to chemical adsorption and the adsorption process is an endothermic reaction 三种价态的镎在硅胶上吸附的等温线符合兰格缪尔吸附等温线的形式,是单分子层吸附;根据克劳修斯-克拉柏龙方程,以1nkd对1 t作图,通过直线斜率计算出吸附热,从吸附热的数据可判断三种价态的镎在硅胶上的吸附属于化学吸附,是吸热的过程;对npov ) 、 np ( v )和np ( vd在硅胶上的吸附进行了比较,提出了三种价态的锋在硅胶上吸附的机理。